Synthesis and Characterization of a new Schiff Base {N-(2-{[(4-bromophenyl)imino]methyl}phenyl)acetamide} and its complexes with some transition metal | ||
| Journal of College of Education for Pure Science | ||
| Article 1, Volume 2, Issue 4, December 2012, Pages 110-117 | ||
| Authors | ||
| Prof. Haider.A.Mahdi; Sajda .S. Afatt | ||
| Abstract | ||
| A new ligand {N-(2-{[(4-bromophenyl)imino]methyl}phenyl)acetamide} (L) and it complexes with Cr(III), Fe(III), Co(II), Ni(II) and Cu(II) were synthesized . These compounds were identified by elemental analysis , Molar conductivity, as well as spectroscopic methods (IR, 1HNMR ,Mass) . It may be concluded that the ligand coordinate through Nitrogen atoms for all the complexes and act as a bidentate ligand which bond through –C=N and –NH groups ,This view is further supported by the appearance of a band corresponding to the metal – nitrogen stretching vibration at )524-550) Cm-1 in the complexes . On the bases of these studies we suggest formation octahedral geometry for all preparded complexes . | ||
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