Synthesis and Characterization of 2-Butoxyethylxanthate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and their Adducts with Nitrogen Base Ligands | ||
| Rafidain Journal of Science | ||
| Article 6, Volume 25, Issue 3, June 2014, Pages 57-64 PDF (0 K) | ||
| DOI: 10.33899/rjs.2014.88644 | ||
| Authors | ||
| Ibraheem A. Al-Qasser; Saad E. Al-Mukhtar; Nada F. Hana | ||
| Abstract | ||
| New complexes and adducts of xanthate of the general formula [M(2-BuoEtxant)2] and [M(2-BuoEtxant)2.nL] Where M= Fe(), Co(), Ni(), Cu() and Zn(), and (2-BuoEtxant)=2-Butoxyethylxanthate, and n=2 when L= pyridine; Isoquinoline, γ-picoline, 3,5-lutidine, n=1 when L= ethylenediamine, (1,10)-phenanthroline, have been prepared and characterized by metal analyses, infrared, conductance measurements, electronic absorption spectra and susceptibility measurements. Magnetic moment and electronic spectra, indicate that the complexes of type [M(2-BuoEtxant)2] are of tetrahedral geometry while the complexes of type [M(2-BuoEtxant)2.nL] have an octahedral geometry. | ||
| Keywords | ||
| Xanthate; iron; cobalt; nickel; copper; Zinc; complexes | ||
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