A. Hussein, A., A. Mohammad, L., A. Hadi, M. (2014). Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand. Alustath, 11(1), 158-165.
Amar A. Hussein; Layla A. Mohammad; Muna A. Hadi. "Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand". Alustath, 11, 1, 2014, 158-165.
A. Hussein, A., A. Mohammad, L., A. Hadi, M. (2014). 'Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand', Alustath, 11(1), pp. 158-165.
A. Hussein, A., A. Mohammad, L., A. Hadi, M. Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand. Alustath, 2014; 11(1): 158-165.

Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand

Baghdad Science Journal
Article 1, Volume 11, Issue 1, February 2014, Pages 158-165
Authors
Amar A. Hussein; Layla A. Mohammad; Muna A. Hadi
Abstract
The New Schiff base ligand 4,4'-[(1,1'-Biphenyl)-4,4'-diyl,bis-(azo)-bis-[2-Salicylidene thiosemicarbazide](HL)(BASTSC)and its complexes with Co(II), Ni(II), and Cu(II) were prepared and characterized by elemental analysis, electronic, FTIR, magnetic susceptibility measurements. The analytical and spectral data showed, the stiochiometry of the complexes to be 1:1 (metal: ligand). FTIR spectral data showed that the ligand behaves as dibasic hexadentate molecule with (N, S, O) donor sequence towards metal ions. The octahedral geometry for Co(II), Ni(II), and Cu(II) complexes and non electrolyte behavior was suggested according to the analysis data.
Keywords
Schiff; base; Metal chelate complexes; octahedral geometry
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