H.Mahmood, T., A.Hassan, E., A.Mubark, L. (2014). Preparation and Characterization of Co(II), Ni(II) and Cu(II) ions Binuclear Complexes with Macrocyclic Schiff Base Derived from Acidhydrazide and α-Hydroxy Ketone. Alustath, 7(2), 1-13. doi: 10.37652/juaps.2013.84990
Tamather H.Mahmood; Esiraa A.Hassan; Luma A.Mubark. "Preparation and Characterization of Co(II), Ni(II) and Cu(II) ions Binuclear Complexes with Macrocyclic Schiff Base Derived from Acidhydrazide and α-Hydroxy Ketone". Alustath, 7, 2, 2014, 1-13. doi: 10.37652/juaps.2013.84990
H.Mahmood, T., A.Hassan, E., A.Mubark, L. (2014). 'Preparation and Characterization of Co(II), Ni(II) and Cu(II) ions Binuclear Complexes with Macrocyclic Schiff Base Derived from Acidhydrazide and α-Hydroxy Ketone', Alustath, 7(2), pp. 1-13. doi: 10.37652/juaps.2013.84990
H.Mahmood, T., A.Hassan, E., A.Mubark, L. Preparation and Characterization of Co(II), Ni(II) and Cu(II) ions Binuclear Complexes with Macrocyclic Schiff Base Derived from Acidhydrazide and α-Hydroxy Ketone. Alustath, 2014; 7(2): 1-13. doi: 10.37652/juaps.2013.84990

Preparation and Characterization of Co(II), Ni(II) and Cu(II) ions Binuclear Complexes with Macrocyclic Schiff Base Derived from Acidhydrazide and α-Hydroxy Ketone

Journal of University of Anbar for Pure Science
Article 34, Volume 7, Issue 2, August 2013, Pages 1-13    PDF (830.94 K)
Document Type: Research Paper
DOI: 10.37652/juaps.2013.84990
Authors
Tamather H.Mahmood* 1; Esiraa A.Hassan2; Luma A.Mubark2
1University of Mosul-College of science
2Mosul University - College of Science
Abstract
The homogenous binuclear complexes of marcocyclic Schiff base ligand obtained from [2+2] condensation reaction between benzion and α ‌‌˗ aminobenzoylhydrazide in presenceof the metal salt , in neutral and alkaline media . The complexes were characterized by quantitive determination of the metal and chloridecontent , molar conductance , spectral and magnetic susceptibility measurement . The different studies revealed that the prepared complexes possess the following formulae [LH4M2X2]and K2[ LM2X2]in neutral and alkaline medium respectively(whereLH4 = macrocyclic Schiff base ligand , M+2=Co,Ni,Cu; X-=NO3,Cl). The complexes of neutral medium are non-electrolytes , six coordinat , while alkaline medium complexes are electrolytes of 2:1 ratio and four coordinate
Keywords
and Cu; Binuclear Complexes; Macrocyclic Schiff Base; Acidhydrazide; Hydroxy Ketone
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