Synthesis and spectroscopic studies of some new oxazepine derivatives throughout [2+5] cycloaddition reactions (IV) | ||
Journal of University of Babylon | ||
Article 1, Volume 22, Issue 1, January 2014, Pages 377-392 | ||
Authors | ||
Alaa J.Mahrath; Saadon A. Aowda; Sabah N Kamil | ||
Abstract | ||
The present work included Condensation reactions of O-tolidine with different aromatic aldehyde in absolute ethanol to give Schiff bases (w13-w16 )in high yield which on reaction with maleic and phthalic anhydride by [2+5] cycloaddition reactions in presence of suitable solvents give the corresponding [1,3]oxazepine -4,7-dione (w13m-w16m ) and [1,3] oxazepine -1,5-dione (w13ph –w16ph) respectively. The structure of new synthesized compounds were monitored by T.L.C and established on the basis of elemental analysis , FT-IR and 1H-NMR. | ||
Keywords | ||
Imines; Tolidine and; oxazepine; dione | ||
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