Adsorption equilibria of methylen blue dye from aqueous solutions by using activated carbon | ||
| Iraqi National Journal Of Chemistry | ||
| Article 1, Volume 0, Issue 51, October 2014, Pages 301-315 | ||
| Authors | ||
| Zahraa Salam Abdalameer; Alaa Hussein Elywe; Ayad Fadhil Alkaim | ||
| Abstract | ||
| Abstract In this study, activated carbon was prepared from coconut shell using sulfuric acid activation (CSAC). Removal of methylene blue (MB) dye from aqueous solution was performed using a batch technique for determination of the effects of initial pH, mass dosage, initial concentration and temperature. Adsorption of methylene blue (MB) was increased with increasing temperature, the maximum percentage removal of 73.14% (adsorption capacity 48.76 mg.g-1), 77.07% (adsorption capacity 51.36 mg.g-1), and 81.47% (adsorption capacity 54.31 mg.g-1) for the temperature of 10 0C, 30 0C, and 55 0C respectively. Equilibrium data were mathematically modeled using the Langmuir, Freundlich, Fritz-Schelunder adsorption models to describe the equilibrium isotherms at different dye concentrations and temperatures, parameters of best-fit model were calculated and discussed. It was found that pH plays a major role in the adsorption process; adsorption capacity was influenced by the physical and surface chemical properties of carbon and the pH of the solution. Change in Gibbs free energy (ΔG), entropy (ΔS), and enthalpy (ΔH) were also calculated, from the adsorption results were found the adsorption process was endothermic. | ||
| Keywords | ||
| coconut shell; Methylen blue; adsorption; Fritz; Schelunder model | ||
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