Synthesis and Characterization of Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) Complexes with Hexa azamacrocyclic Ligands Derived from Thiosemicarbazide | ||
| Journal of Education and Science | ||
| Article 6, Volume 24, Issue 4, December 2011, Pages 60-67 PDF (0 K) | ||
| DOI: 10.33899/edusj.1970.58957 | ||
| Author | ||
| Saad K. Dawood* | ||
| Department of Chemistry, College of Science, University of Mosul, Mosul, Iraq | ||
| Abstract | ||
| Abstract: Some transition metal (II) complex are synthesized with thiosemicarbazide Ligands L1= dicyclohexen [1,6,7,9,14,15] hexaaza [2,5,10,3] tetra one [8,13] dithiacyclohexadecane and L2= dicyclohexyl [1,6,7,9,14,15] hexaaza [2,5, 10, 13] tetraone [8,13] dithiaCyclohexadecane. These complexes are characterized by elemental analysis, molar conductance magnetic susceptibility measurements, IR, electronic spectral studies. The molar conductance measurements of the complexes in DMSO correspond to non-electrolytic nature and the complexes may have octahedral geometry. | ||
| Keywords | ||
| synthesis; Mn(II); Fe(II); Co(II); Ni(II); Cu(II); Zn(II); Hexa azamacrocyclic; Thiosemicarbazide | ||
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