Investigation of New Tetra Dentate Macrocyclic [N4] Ligand and it's Complexes with Transition Metal's | ||
| Journal of Education and Science | ||
| Article 3, Volume 24, Issue 2, June 2011, Pages 22-27 PDF (0 K) | ||
| DOI: 10.33899/edusj.1999.58727 | ||
| Authors | ||
| Saad K. Dawood* ; Sahbaa A. Al-Sabaawi | ||
| Department of Chemistry, College of Science, University of Mosul, Mosul, Iraq | ||
| Abstract | ||
| Abstract : This paper describes the preparation and study of a number of transition metal Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) with the ligand (2,9-diamin-5,7,12,14-tetraazo-1,4,8,11-tetra oxo-6,13-dithiacyclotetra-decane)L1 . These complexes also reacted with 4-methyl pyridine (γ-picoline) L2 to form 1:2 adducts in which the ligand act as a monodentate ligand. All these complexes and the adduct characterized by microanalytical (M%), molar conductance measurements, magnetic susceptibility measurements, IR, and electronic spectral. | ||
| Keywords | ||
| Tetra Dentate Macrocyclic; Metal Complexes; Transition Metal's | ||
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