Studying the effect of adding Magnesium oxide-nano to poly hydroxamic acid on the adsorption Isotherms of V+5 and Fe+3 | ||
Journal of University of Anbar for Pure Science | ||
Article 20, Volume 17, Issue 2, December 2023, Pages 134-143 PDF (792.92 K) | ||
Document Type: Research Paper | ||
DOI: 10.37652/juaps.2023.141920.1101 | ||
Authors | ||
Soraa Ahmed Mukhlif* 1; Saddaa Abed Abedullah Jamal2 | ||
1Department of Chemistry, College of Education for Pure Science , University Of Anbar, Ramadi, Iraq; | ||
2Department of Chemistry, College of Education for Women, University Of Anbar, Ramadi, Iraq. | ||
Abstract | ||
This study involves preparations of polymers poly (styrene -co-acrylic) and poly (styrene -co-methyl methacrylate) via free radical polymerization at temperatures between (70 and 80 °C) with conversion rates of 10% for initiator benzoyl peroxide. Through neutralizing polymer with hydroxyl amine hydro-chloride in a base medium pH = 12–13 utilizing potassium hydroxide (KOH) with the thermal escalation for 120 hrs, the ester group in the resulting polymers have been converted to poly hydroxamic acid (HA). The resulting compound has then been identified through infra-red spectroscopy (FT-IR) and NMR. Magnesium oxide-nano was mixed thoroughly with the corresponding amount of poly HA. Prior to and following the addition of Magnesium oxide - nano to poly (styrene -Co- methyl metha acrylic) HA, the adsorption capacity regarding the ferric and vanadium ions was evaluated. Effects of temperature, time, and PH on the capacity of the adsorption have been investigated. The rate of adsorption reduces as acidity rises and falls from pH=6, and adsorption heat has been calculated at 2 temperature degrees. The capacity for adsorption increases with the increase in time, and the maximum adsorption capacity has been at pH = 6. According to values of the adsorption temperature, ferric ion adsorption is physical whereas vanadium ion adsorption is chemical. | ||
Keywords | ||
polymers,,,; ,،styrene,,,; ,،methacrylate,,,; ,،nanoparticles | ||
References | ||
[1] Nasrollahzadeh, M., Sajadi, S. M., Sajjadi, M., & Issaabadi, Z. (2019). An introduction to nanotechnology. In Interface science and technology (Vol. 28, pp. 1-27). Elsevier.
[2] Zaib, S., & Iqbal, J. (2019). Nanotechnology: Applications, techniques, approaches, & the advancement in toxicology and environmental impact of engineered nanomaterials. Importance & Applications of Nanotechnology, 8.
[3] Carroll, L. S. L. (2017). A comprehensive definition of technology from an ethological perspective. Social Sciences, 6(4), 126.
[4] Gohil, S. V., Suhail, S., Rose, J., Vella, T., & Nair, L. S. (2017). Polymers and composites for orthopedic applications. In Materials for Bone Disorders (pp. 349-403). Academic Press.
[5] Seo, Y., Jang, S., Ahn, S., Mishra, A. K., Kim, J. K., & Lee, W. B. (2018). Phase Behavior of 18-Arm Star-Shaped Polystyrene-block-poly (methyl methacrylate) Copolymers with Different Second Block Initiations. Macromolecules, 51(7), 2750-2755.
[6] Odian, George. "Principles of Polymerization, John Wiley& Sons." Inc.: Hoboken, NJ (2004).
[7] Sharma, R. K. (2001). Design, synthesis, and application of chelating polymers for separation and determination of trace and toxic metal ions. A green analytical method. Pure and Applied Chemistry, 73(1), 181-186.
[8] Citarella, A., Moi, D., Pinzi, L., Bonanni, D., & Rastelli, G. (2021). Hydroxamic Acid Derivatives: From Synthetic Strategies to Medicinal Chemistry Applications. ACS omega, 6(34), 21843-21849.
[9] Cotton, F. A., Wilkinson, G., & Gaus, P. L. (1995). Basic inorganic chemistry. John Wiley & Sons.
[10] Saratale, R. G., Sivapathan, S., Saratale, G. D., Banu, J. R., & Kim, D. S. (2019). Hydroxamic acid mediated heterogeneous Fenton-like catalysts for the efficient removal of Acid Red 88, textile wastewater and their phytotoxicity studies. Ecotoxicology and environmental safety, 167, 385-395.
[11] Al-Jumaili, N. F., (2020) “Study of adsorption of some heavy metal elements on polyhydroxamic acid prepared from copolymerization (styrene-methyl methacrylate) and its use in water purification,” Master’s thesis, College of Education for Pure Sciences, Department of Chemistry.
[12] Saratale, R. G., Sivapathan, S., Saratale, G. D., Banu, J. R., & Kim, D. S. (2019). Hydroxamic acid mediated heterogeneous Fenton-like catalysts for the efficient removal of Acid Red 88, textile wastewater and their phytotoxicity studies. Ecotoxicology and environmental safety, 167, 385-395.
[13] Rahman, M. L., Wong, Z. J., Sarjadi, M. S., Abdullah, M. H., Heffernan, M. A., Sarkar, M. S., & O’Reilly, E. (2021). Poly(hydroxamic acid) ligand from palm-based waste materials for removal of heavy metals from electroplating wastewater. Journal of Applied Polymer Science, 138(2). https://doi.org/10.1002/APP.49671
[14] Cao, X., Wang, Q., Wang, S., & Man, R. (2022). A novel polystyrene-poly(hydroxamic acid) interpenetrating polymer network and its adsorption towards rare earth ions. Journal of Rare Earths, 40(1), 127–134. https://doi.org/10.1016/J.JRE.2020.11.017
[15] Duan, G., Li, X., Ma, X., Zhong, W., & Wang, S. (2023). High-efficiency adsorption removal for Cu(II) and Ni(II) using a novel acylamino dihydroxamic acid chelating resin. ScTEn, 864, 160984. https://doi.org/10.1016/J.SCITOTENV.2022.160984
[16] Li, X., Silge, S., Saal, A., Kircher, G., Koynov, K., Berger, R., & Butt, H. J. (2021). Adaptation of a styrene-acrylic acid copolymer surface to water. Langmuir, 37(4), 1571- 1577.
[17] Haron, M. J., Tiansih, M., Ibrahim, N. A., Kassim, A., & Yunus, W. M. Z. W. (2009). Sorption of Cu (II) by poly (Hydroxamic Acid)chelating exchanger prepared from polymethyl acrylate grafted oil palm empty fruit bunch (OPEFB). BioResources, 4(4), 1305-1318.
[18] Jamal, S. A. A., & Alywee, A. K. (2012). Study of the Sorption Kinetics of Fe (III) by Polyhydroxamic acid Chelating Exchanger Prepared from Polystyrene-Co-Methyl methacrylate. Journal of Applicable Chemistry, 1(3), 433-441.
[19] Beni, A. A., Esmaeili, A., & Behjat, Y. (2021). Invent of a simultaneous adsorption and separation process based on dynamic membrane for treatment Zn (II), Ni (II) and, Co (II) industrial wastewater. Arabian Journal of Chemistry, 14(7), 103231.
[20] Fatima, K. I., & Saddaa, A. A. (2021). STUDY OF THE KINETICS OF SEQUESTRATION OF SOME HEAVY METAL BY POLY HYDROXAMIC ACID AS A CHELATING COMPOUND. Turkish Journal of Physiotherapy and Rehabilitation, 32(3), 8607-8616.
[21] Rahman, M. L., Mandal, B. H., Sarkar, S. M., Wahab, N. A. A., Yusoff, M. M., Arshad, S. E., & Musta, B. (2016). Synthesis of poly (hydroxamic acid) ligand from polymer grafted khaya cellulose for transition metals extraction. Fibers and Polymers, 17(4), 521-532.
[22] Cao, X., Wang, Q., Wang, S., & Man, R. (2020). Preparation of a novel polystyrene-poly (hydroxamic acid) copolymer and its adsorption properties for rare earth metal ions. Polymers, 12(9), 1905.
[23] Yayayürük, A. E. (2017). The Use of Acrylic-Based Polymers in Environmental Remediation Studies. In Acrylic Polymers in Healthcare. IntechOpen. | ||
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