Mahmood, N., Hikmat, M. (2023). The Effect of Calcium Carbonate-Nanoparticle on the Mechanical and Thermal Properties of Polymers Utilizing Different Types of Mixing and Surface Pre-Treatment: A Review Paper. Alustath, 41(12), 1497-1515. doi: 10.30684/etj.2023.142219.1523
Nashwan Q. Mahmood; Mohammed Hikmat. "The Effect of Calcium Carbonate-Nanoparticle on the Mechanical and Thermal Properties of Polymers Utilizing Different Types of Mixing and Surface Pre-Treatment: A Review Paper". Alustath, 41, 12, 2023, 1497-1515. doi: 10.30684/etj.2023.142219.1523
Mahmood, N., Hikmat, M. (2023). 'The Effect of Calcium Carbonate-Nanoparticle on the Mechanical and Thermal Properties of Polymers Utilizing Different Types of Mixing and Surface Pre-Treatment: A Review Paper', Alustath, 41(12), pp. 1497-1515. doi: 10.30684/etj.2023.142219.1523
Mahmood, N., Hikmat, M. The Effect of Calcium Carbonate-Nanoparticle on the Mechanical and Thermal Properties of Polymers Utilizing Different Types of Mixing and Surface Pre-Treatment: A Review Paper. Alustath, 2023; 41(12): 1497-1515. doi: 10.30684/etj.2023.142219.1523

The Effect of Calcium Carbonate-Nanoparticle on the Mechanical and Thermal Properties of Polymers Utilizing Different Types of Mixing and Surface Pre-Treatment: A Review Paper

Engineering and Technology Journal
Article 7, Volume 41, Issue 12, December 2023, Pages 1497-1515    PDF (1.57 M)
Document Type: Review Paper
DOI: 10.30684/etj.2023.142219.1523
Authors
Nashwan Q. Mahmood* ; Mohammed Hikmat
Mechanical and Manufacturing Engineering, College of Engineering, Sulaimani Polytechnic University, Sulaimani, Kurdistan, Iraq.
Abstract
The effect of calcium carbonate nanoparticles (CaCO3) on the mechanical and thermal properties of various polymers was investigated in this review. The results were compared to scholarly research published between 2002-2022. Different polymers were evaluated, including Polypropylene (PP), High-density polyethylene (HDPE), Polyvinyl chloride (PVC), Low-density polyethylene (LDPE), Polyethylene (PE), and natural rubber (NR). Through this work, the effect of CaCO3 nanoparticles that act as fillers in polymeric materials has been reviewed. It can be concluded that mechanical and thermal properties can be decreased, increased, or unchanged by increasing and decreasing the fillers to obtain optimal results. It is reasonable to conclude that most papers with nano-CaCO3 showed improvements in appreciable mechanical and thermal properties. In general, the term "surface modification of inorganic fillers" refers to the coating of the fillers with organic materials, which can be done by physical and chemical interactions between the modifiers and the fillers. The reviewed articles revealed that modification of CaCO3 nanoparticles with surface pre-treatment fillers caused enhancement of the mechanical properties of the polymeric matrix twice and prevented the agglomeration of particles in the matrix. Various mixing methods have been used, the most significant being a twin screw extruder, mechanical stirrer, and two-roll mill.

Highlights
  • he nano-CaCO3 showed appreciable mechanical and thermal properties
  • The modification of CaCO3 nanoparticles with surface pre-treatment caused enhancement of the mechanical properties twice
  • Surface pre-treatment prevented the agglomeration of particles in the matrix
  • The twin screw extruder method showed appreciable results
Keywords
CaCO3 filler; Polymer matrix; Nanocomposite; Thermo-mechanical properties; Surface pre-treatment
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