Ghazi Kadhim AlFalah, M., Saracoglu, M., Yilmazer, M., Kandemirli, F. (2023). Corrosion inhibition performance of 2- Fluorophenyl-2, 5-dithiohydrazodicarbonamide for copper in 3.5%NaCl Media: Experimental and Monte Carlo insights. Alustath, 16(3), 150-159. doi: 10.30772/qjes.2023.178995
Mothana Ghazi Kadhim AlFalah; Murat Saracoglu; Mehmet Izzettin Yilmazer; Fatma Kandemirli. "Corrosion inhibition performance of 2- Fluorophenyl-2, 5-dithiohydrazodicarbonamide for copper in 3.5%NaCl Media: Experimental and Monte Carlo insights". Alustath, 16, 3, 2023, 150-159. doi: 10.30772/qjes.2023.178995
Ghazi Kadhim AlFalah, M., Saracoglu, M., Yilmazer, M., Kandemirli, F. (2023). 'Corrosion inhibition performance of 2- Fluorophenyl-2, 5-dithiohydrazodicarbonamide for copper in 3.5%NaCl Media: Experimental and Monte Carlo insights', Alustath, 16(3), pp. 150-159. doi: 10.30772/qjes.2023.178995
Ghazi Kadhim AlFalah, M., Saracoglu, M., Yilmazer, M., Kandemirli, F. Corrosion inhibition performance of 2- Fluorophenyl-2, 5-dithiohydrazodicarbonamide for copper in 3.5%NaCl Media: Experimental and Monte Carlo insights. Alustath, 2023; 16(3): 150-159. doi: 10.30772/qjes.2023.178995

Corrosion inhibition performance of 2- Fluorophenyl-2, 5-dithiohydrazodicarbonamide for copper in 3.5%NaCl Media: Experimental and Monte Carlo insights

Al-Qadisiyah Journal for Engineering Sciences
Volume 16, Issue 3, September 2023, Pages 150-159    PDF (1.01 M)
Document Type: Research Paper
DOI: 10.30772/qjes.2023.178995
Authors
Mothana Ghazi Kadhim AlFalah* 1; Murat Saracoglu2; Mehmet Izzettin Yilmazer3; Fatma Kandemirli4
1Kastamonu University, Faculty of Engineering and Architecture, Metallurgy and Materials Engineering Department, 37150, Kastamonu, Türkiye
2Erciyes University, Faculty of Education, 38039, Kayseri, Türkiye
3Erciyes University, Faculty of Science, Department of Chemistry, 38039, Kayseri, Türkiye
4Kastamonu University, Faculty of Engineering and Architecture, Biomedical Engineering Department, 37150, Kastamonu, Türkiye
Abstract
Most industries struggle with corrosion. Corrosion inhibitors are needed in these sectors. Eco-friendly corrosion inhibitors should be effective even at low concentrations. In this work, the compound 2- Fluorophenyl-2, 5- dithiohydrazodicarbonamide (2F-TSC) was utilized as a corrosion inhibitor for copper in a 3.5% NaCl solution. The inhibitor efficiency was calculated by using a series of electrochemical methods like, open circuit potential (OCP), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS). All tests have been done in a stagnant condition. The results show that the compound 2F-TSC looked to be of mixed type. Furthermore, the maximum inhibitor efficiency was reached at 99.2% at 10-2 M 2F-TSC and 5 h. The adsorption of 2F-TSC on the copper surface in 3.5% NaCl obeyed the Langmuir isotherm with a negative value of the standard Gibbs free energy of adsorption of -35.4 kJ/mol (chemisorption and physisorption). SEM, EDX, and AFM confirmed the presence of 2F-TSC on the surface of copper. The adsorption of the inhibitor molecules on the Cu (111) surface was further verified by a Monte Carlo simulation study. The results approved that the 2F-TSC can be utilized as a corrosion inhibitor for copper in an aggressive solution (3.5% NaCl).
Keywords
Copper; Corrosion resistance; EIS; Langmuir; Monte Carlo simulation
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