Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands | ||
| Journal of Education and Science | ||
| Article 5, Volume 32, Issue 3, September 2023, Pages 47-59 PDF (774.12 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.33899/edusj.2023.139116.1349 | ||
| Authors | ||
| Mahameed Ameen Ali Al-Badrane* 1; Fadia J Ahmed2 | ||
| 1Dept.Chemistry,Education Collegefor Pure Science, University of Mosul | ||
| 2Department of Chemistry, college of education for pure science | ||
| Abstract | ||
| This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions Mn(II) , Fe(II) , Co(II) and through the interaction with ligand (decyl xanthate potassium) and complexes of formula [M(DEXANT)2] were formed , as : M= Mn(II) , Fe(II) , Co(II) and then the interaction of these complexes with Lewis bivalve bases , to give complexes with the formula [M(DEXANT)2 . L], where : L= 1,10-phenanthroline , 8-hydroxyquinoline, 2,2-Pipyridine. The prepared complexes were characterized by melting point , atomic absorption, micro elemental analysis , infrared , nuclear magnetic resonance spectrum of the proton , molar electrical conductivity , electronic absorption spectra and susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type [M(DEXANT)2] had a tetrahedral geometry, while complexes of type [M(DEXANT)2.L] had an octahedral geometry,The conductivity measurements proved the non-electrolytic behavior of all compounds . | ||
| Keywords | ||
| Xanthate,,; ,،؛Manganese(II),,; ,،؛Iron(II),,; ,،؛Cobalt(II),,; ,،؛Complexes | ||
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