Preparation of poly hydroxamic acid from poly (styrene –methyl metha acrylate) and study of the kinetics of nickel ion sorption by the prepared acid | ||
Journal of University of Anbar for Pure Science | ||
Article 7, Volume 15, Issue 2, December 2021, Pages 45-52 PDF (1.06 M) | ||
Document Type: Research Paper | ||
DOI: 10.37652/juaps.2022.172452 | ||
Authors | ||
Fatima Khalil Ibrahim* 1; Saddaa Abedullah2 | ||
1Chemistry Department: College of Science - University of Anbar - Iraq. | ||
2Chemistry Department: Education College for Women- University of Anbar- Iraq. | ||
Abstract | ||
In this paper, the copolymer (styrene-methyl methacrylate) was prepared by using free radical polymerization for the copolymerization between methyl methacrylate and styrene in an equal molar mixing ratio and using benzoyl peroxide as a starter at a temperature of 70 °C. Then the prepared copolymer was converted to poly hydroxamic acid, and this was done by reacting the copolymer with hydroxylamine hydrochloride at a base medium of = 13 using sodium hydroxide with heat escalation for a period of 70 °C. The nickel ion sorption capacity of the resultant product was evaluated using poly hydroxamic acid and spectroscopic FT-IR. As well as studying the effect of time, temperature, and acidity function on the sorption capacity by chelating poly hydroxamic acid. Where it was shown that the capacity of adsorption increases with increasing time and decreases with increase in temperature mediated by poly hydroxamic acid. The equations of Arrhenius and Vant Hof were used, and from the enthalpy values, it was shown that the reaction was exothermic, and from the negative compression energy values, it was found that the reaction is spontaneous and the type of physical detention is mediated by poly hydroxamic acid. | ||
Keywords | ||
poly hydroxamic acid; poly; styrene-methyl methacrylate; sorption capacity; hydroxamic acid | ||
References | ||
[1] Smith Sockwell, A. K. (2018). Multidentate Ligand Design for the F-Elements.
[2] Sockwell, A. K., & Wetzler, M. (2019). Beyond biological chelation: coordination of f‐block elements by polyhydroxamate ligands. Chemistry–A European Journal, 25(10), 2380-2388.
[3] Rahman, M. L., Sarkar, S. M., Yusoff, M. M., & Abdullah, M. H. (2017). Optical detection and efficient removal of transition metal ions from water using poly (hydroxamic acid) ligand. Sensors and Actuators B: Chemical, 242, 595-608.
[4] Saratale, R. G., Sivapathan, S., Saratale, G. D., Banu, J. R., & Kim, D. S. (2019). Hydroxamic acid mediated heterogeneous Fenton-like catalysts for the efficient removal of Acid Red 88, textile wastewater and their phytotoxicity studies. Ecotoxicology and environmental safety, 167, 385-395.
[5] Sockwell, A. K. S. (2018). Multidentate Ligand Design for the F-elements (Doctoral dissertation, Clemson University).
[6] Tulaib, S. F., Abd Khthem, M., & Hussien, M. O. (2010). Preparation of new complexes for hydroxamic acids with Iron; Copper and Cobalt and studying their spectrum properties and biological activity.
[7] Jamal, S. A. A. (2012). Study of the sorption kinetic of Fe (III) by poly (Hydroxamic acid) chelating exchanger prepared from poly (Styrene-Co-Ethylacrylate). Iraqi National Journal Of Chemistry, (47).
[8] Patel, A. (2016). Synthesis and antimicrobial activity of some hydroxamic acids.
[9] Gamal, S. A. A. (2013). Preparation of poly (acro-yellow hydroxamic acid) from the polymer (methyl acrylate) and study use it in the water purification from heavy metal elements. JOURNAL OF EDUCATION AND SCIENCE, 26(5), 314-324.
[10] Abedullah Jamal, S. A., Hmadi, W. F., & Al-Obaidi, O. (2020). Preparation Some of Hydroxamic Acid Derivatives from Honey Wax Compounds and Study the Biological Activity on Cancerous Tumors. Systematic Reviews in Pharmacy, 11(2).
[11] Nipithakul, T., & Sintasanai, K. (2017). Study on Preparation Conditions of Poly (hydroxamic acid) from Poly (acrylamide)-grafted-polyethylene Film. In 55. Kasetsart University Annual Conference, Bangkok (Thailand), 31 Jan-3 Feb 2017.
[12] Rahman, M. L., Mandal, B. H., Sarkar, S. M., Wahab, N. A. A., Yusoff, M. M., Arshad, S. E., & Musta, B. (2016). Synthesis of poly (hydroxamic acid) ligand from polymer grafted khaya cellulose for transition metals extraction. Fibers and Polymers, 17(4), 521-532.
[13] Haron, M. J., Tiansih, M., Ibrahim, N. A., Kassim, A., & Yunus, W. M. Z. W. (2009). Sorption of Cu (II) by poly (Hydroxamic Acid) chelating exchanger prepared from polymethyl acrylate grafted oil palm empty fruit bunch (OPEFB). BioResources, 4(4), 1305-1318.
[14] Suzuki, M., Endo, M., Shinohara, F., Echigo, S., & Rikiishi, H. (2009). Enhancement of cisplatin cytotoxicity by SAHA involves endoplasmic reticulum stress-mediated apoptosis in oral squamous cell carcinoma cells. Cancer chemotherapy and pharmacology, 64(6), 1115-1122.
[15] Piro, G., Roca, M. S., Bruzzese, F., Carbone, C., Iannelli, F., Leone, A., ... & Di Gennaro, E. (2019). Vorinostat potentiates 5-fluorouracil/Cisplatin combination by inhibiting chemotherapy-induced EGFR nuclear translocation and increasing Cisplatin uptake. Molecular cancer therapeutics, 18(8), 1405-1417.
[16] Beaugeard, V., Muller, J., Graillot, A., Ding, X., Robin, J. J., & Monge, S. (2020). Acidic polymeric sorbents for the removal of metallic pollution in water: A review. Reactive and Functional Polymers, 104599.
[17] Ibrahim, F. K., & Abedullah, S. A.(2021). STUDY OF THE KINETICS OF SEQUESTRATION OF SOME HEAVY METAL BY POLY HYDROXAMIC ACID AS A CHELATING COMPOUND. Turkish Journal of Physiotherapy and Rehabilitation, 32, 3.
[18] Pertile, E., Dvorský, T., Václavík, V., & Heviánková, S. (2021). Use of Different Types of Biosorbents to Remove Cr (VI) from Aqueous Solution. Life, 11(3), 240.
[19] Noguchi, A., Nishida, T., Hatta, H., Takagi, K., Kakiuchi, T., Tanaka, S., ... & Imura, J. (2021). Efficacy of Cetuximab and 4-PBA Combination Therapy in Human Oral Squamous Cell Carcinoma Cells.
[20] Pan, W., Perrotta, J. A., Stipanovic, A. J., Nomura, C. T., & Nakas, J. P. (2012). Production of polyhydroxyalkanoates by Burkholderia cepacia ATCC 17759 using a detoxified sugar maple hemicellulosic hydrolysate. Journal of Industrial Microbiology and Biotechnology, 39(3), 459-469.
[21] Ngah, W. W., & Hanafiah, M. A. K. M. (2008). Biosorption of copper ions from dilute aqueous solutions on base treatedrubber (Hevea brasiliensis) leaves powder: kinetics, isotherm, and biosorption mechanisms. Journal of Environmental Sciences, 20(10), 1168-1176.
[22] Pisano, R., Anakkar, A., Pellegrino, E. M., & Nagels, M. (2019). Thermodynamic foundations of physical chemistry: reversible processes and thermal equilibrium into the history. Foundations of Chemistry, 21(3), 297-323. | ||
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