Experimental Study of 2-Amino-5-(4- nitrophenyl)-1, 3, 4-Thiadiazole for MS in HCl Solution | ||
Engineering and Technology Journal | ||
Article 3, Volume 37, 2C, May 2019, Pages 214-218 PDF (229.55 K) | ||
Document Type: Research Paper | ||
DOI: 10.30684/etj.37.2C.3 | ||
Authors | ||
Talib K. Abed1; Khalida F. Al-Azawi2; Shaimaa H. Jaber3; Ahmed A. Al-Amiery4; Shaimaa B. Al-Baghdadi4 | ||
1Environmental Research Center, University of Technology - Iraq | ||
2Applied Science Department, University of Technology - Iraq | ||
3Chemistry Department, College of Science, Al-Mustansiriya University - Iraq | ||
4Energy and Renewable Energies, Technology Center, University of Technology - Iraq | ||
Abstract | ||
The present work aims to study the inhibition performance of new organic inhibitor namely ANTD “2-amino-5-(4-nitrophenyl)-1,3,4- thiadiazole” on corrosion of mild steel (MS) in HCl environment at the concentration of 1.0 M through using weight loss techniques. Weight lost measurements demonstrates the presence of a film on MS surface in existence of organic substance. The inhibition performance of ANTD at various concentrations for mild steel increases with increasing concentration and with an increased in the immersion time and decreased with raising temperatures degrees. The optimal inhibition efficiency of (ANTD), 82%, was achieved for mild steel when immersed with the highest utilized concentration for 6 hrs. | ||
Keywords | ||
Mild Steel; Corrosion inhibition; ANTD | ||
References | ||
[1] S.K. Shukla, A. Singh and A. Quraishi, “Efficient corrosion inhibitors for mild steel in hydrochloric acid solution,” Int. J. Electrochem. Sci., Vol. 7, pp. 3371–3389, 2012. [2] X. Bin, Y. Wenzhong, L. Ying, Y. Xiaoshuang, G. Weinan and C. Yizhong, “Experimental and theoretical evaluation of two pyridinecarboxaldehyde thiosemicarbazone compounds as corrosion inhibitors for mild steel in hydrochloric acid solution,” Corros. Sci., Vol. 78, pp. 260–268, 2014. [3] A. Kosari, M.H. Moayed, A. Davoodi, R. Parvizi, M. Momeni, H. Eshghi and H. Moradi, “Electrochemical and quantum chemical assessment of two organic compounds from pyridine derivatives as corrosion inhibitors for mild steel in HCl solution under stagnant condition and hydrodynamic flow,” Corros. Sci., Vol. 78, pp. 138–150, 2014. [4] M. Bobina, A. Kellenberger, J. Millet, C. Muntean and N. Vaszilcsin, “ Corrosion resistance of carbon steel in weak acid solutions in the presence of L-histidine as a corrosion inhibitor,” Corros. Sci., Vol. 69, pp. 389–395, 2013. [5] L. Fragoza-Mar, O. Olivares-Xometl, M. DomínguezAguilar, E. Flores, P. Lozada and F. Jiménez-Cruz, “Corrosion inhibitor activity of 1,3-diketone malonates for mild steel in aqueous hydrochloric acid solution”, Corros. Sci., Vol. 61, pp. 171–184, 2012. [6] P.S. Desai and S.M. Kapopara, “Inhibiting effect of anisidines on corrosion of aluminum in hydrochloric acid,” Indian Journal of Chemical Technology, Vol. 16, Part 6, pp. 486–491, 2009. [7] A.S. Fouda, G.Y. Elewady, and M.N. El-Haddad, “Corrosion inhibition of carbon steel in acidic solution using some azodyes,” Canadian Journal on Scientific and Industrial Research, Vol. 2, Part 1, pp. 1–18, 2011. [8] M. Ramananda Singh, K. Bhrara, and G. Singh, “The inhibitory effect of diethanolamine on corrosion of mild steel in 0.5M sulphuric acid medium,” Portugaliae Electrochimica Acta, Vol. 26, pp. 479–492, 2008. [9] V.S. Sastri, “Green Corrosion Inhibitors: Theory and Practice,” John Wiley & Sons, New York, NY, USA, 2011. [10] A. A. Al-Amiery, A.Y. Musa, A.H. Kadhum, A.B. Mohamad, “The use of umbelliferone in the synthesis of new heterocyclic compounds,” Molecules, Vol. 16, pp. 6833–6843, 2011. [11] A.A.H. Kadhum, A.A. Al-Amiery, A.Y. Musa, A.B. Mohamad, “The Antioxidant Activity of New Coumarin Derivatives,” Int. J. Mol. Sci., Vol. 12, pp. 5747–5761, 2011. [12] A.A. Al-Amiery, A.A.H. Kadhum and A.A. Mohamad, “Antifungal Activities of New Coumarins,” Molecules, Vol. 17, pp. 5713–5723, 2012. [13] Y.K. Al-Majedy, D.L. Al-Duhaidahawi, K.F. AlAzawi, A.A. Al-Amiery, A.A.H. Kadhum and A.B. Mohamad, “Coumarins as Potential Antioxidant Agents Complemented with Suggested Mechanisms and Approved by Molecular Modeling Studies,” Molecules , Vol. 21, pp. 135, 2016. [14] A.A. Al-Amiery, Y.K. Al-Majedy, A.A.H. Kadhum and A.B. Mohamad, “New Coumarin Derivative as an Eco-Friendly Inhibitor of Corrosion of Mild Steel in Acid Medium,” Molecules, Vol. 20, pp. 366–383, 2015. [15] K.F. Al-azawi, “Corrosion Inhibition of Mild Steel in Hydrochloric Acid Solution by an Isatin-aniline Compound,” Molecules, Vol. 36, Part B, No. 2, 2018. [16] A.A.H. Kadhum, A. B. Mohamad, L.A. Hammed, A.A. Al-Amiery, N. H. San, A.Y. Musa, “ Inhibition of Mild Steel Corrosion in Hydrochloric Acid Solution by New Coumarin,” Materials, Vol. 7, pp. 4335–4348, 2014. [17] A.A. Al-Amiery, A.A.H., Kadhum, A. Kadihum, A.B. Mohamad, C.K. How, S. Junaedi, “Inhibition of Mild Steel Corrosion in Sulfuric Acid Solution by New Schiff Base,” Materials, Vol. 7, pp. 787–804, 2014. [18] A.A. Al-Amiery, A.A.H. Kadhum, A.H.M. Alobaidy, A.B. Mohamad, P. S. Hoon, “Novel Corrosion Inhibitor for Mild Steel in HCl,” Materials, Vol. 7, pp. 662–672, 2014. [19] A.A. Al-Amiery, A.A.H. Kadhum, A.B. Mohamad, S. Junaedi, “Novel Hydrazinecarbothioamide as a Potential Corrosion Inhibitor for Mild Steel in HCl,” Materials, Vol. 6, pp. 1420–1431, 2013. [20] A. Standard. G1–03. “Standard Practice for preparing, cleaning, and evaluating corrosion test specimens,” Annual Book ASTM Standards, Vol. 3, pp. 17–25, 2003. [21] Q. Deng, H-W. Shi, N-N. Ding, B-Q .Chen, X-P. He, G .Liu, et al. “Novel triazolyl bisamino acid derivatives readily synthesized via click chemistry as potential corrosion inhibitors for mild steel in HCl,” Corros .Sci. Vol. 57, pp. 220–227, 2012. [22] Z .Tao, He W, S .Wang, S. Zhang, G. Zhou, “A study of differential polarization curves and thermodynamic properties for mild steel in acidic solution with nitro phenyl triazole derivative,” Corros. Sci, Vol. 60, pp. 205–213, 2012. [23] K.F. Al-Azawi, I.M. Mohammed, S. B. Al-Baghdadi, T. A. Salman, H. A. Issa, A.A. Al-Amiery, T.S. Gaaz and A. A. H. Kadhum, “Experimental and quantum chemical simulations on the corrosion inhibition of mild steel by 3- ((5-(3,5- dinitrophenyl)-1,3,4-thiadiazol-2-yl) imino)indolin-2-one,” Results Phys., Vol. 9, pp. 278–283, 2018. [24] C. Verma, L.O. Olasunkanmia, E.E. Ebensoa, M.A. Quraishi, “Substituents effect on corrosion inhibition performance of organic compounds in aggressive ionic solutions: A review,” J. Mol. Liq., Vol. 25, pp. 100–118, 2018. | ||
Statistics Article View: 193 PDF Download: 186 |