Synthesis and Characterization Complexes Of Cr(III),Mo(V) and W(VI) with Schiff Base Derivatives from (2-hydroxy-benzylidene) and Urea or Thiourea and Study of its biological activity. | ||
| Journal of University of Anbar for Pure Science | ||
| Article 11, Volume 3, Issue 3, December 2009, Pages 35-39 PDF (613.85 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2009.15611 | ||
| Author | ||
| Omar Hamad Shehab* | ||
| University of Anbar - Women Education College | ||
| Abstract | ||
| Acetylenic amine (N,N-Bis propargy piperazine) were synthesized and diagnosed in spectroscopic method (Uv-visibl and IR) and (C.H.N) analysis . Preparing and studying new complexes by using ligand that from acetylenic amine which using this purpose at the first time with metal chlorides(Mo+3 ,Cr+5 ,W+6 ,Fe+3 ). Studying of complexes by using suitable methods have been diagnosed in Uv-Visible, IR, Magnetic susceptibility , atomic absorption ,electric conductivity measurement and molar ratio, all result obtained from different techniques above which were found that their corresponding with the proposed structures for the prepared complexes . Complexes appeared liquid crystal properties therefore they have been studied careful (∆H, ∆S) of liquid crystal stages for both changes calculated which were found that their corresponding with the data in literature. | ||
| Keywords | ||
| synthesis; Characterization; complexes; III; Schiff base; hydroxy; benzylidene; urea; thiourea; biological activity | ||
| References | ||
|
1- A.G.Brown and S.M.Roberty,"Recent Advances in the chemistry of β-lactam Antibiotics." The Royal Society of chemistry , London(ed.) (1984).
2-J.P.Anacona, Synthesis and antibacterial activity of some metal complexes of beta-lactamantibiotics, J. Coord. Chem., 54,pp355-365,(2001).
3-F.Forghierri,C .Preti,G.Tosi and P.Zonnini, preparation and pharmacological of some novel metal complexes .,Aust. J .Chem. , 36,1125,(1983).
4-M.S.Lqbal, A.R. Ahmed, M. Sabir and S.M. Asad , preparation characterization and biological evaluation of Cu(II) and Zn(II) Complexes with Cephalexine ,J.Pharm. Phamacol,51,371 (1999).
5-G.B.Mahto, J.Indian.C hem.Soc.,57 ,481 (1980).
6- U.K.Mauthy, N.D.Jaghik and M.GPrjpe, J.Indian.Chem.Soc.,53,419(1976).
7- Tamura,J., Tetrahedron Lett,24,5749(1983). | ||
|
Statistics Article View: 145 PDF Download: 123 |
||