SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA | ||
Journal of University of Anbar for Pure Science | ||
Article 12, Volume 1, Issue 3, December 2007, Pages 45-51 PDF (413.16 K) | ||
Document Type: Research Paper | ||
DOI: 10.37652/juaps.2007.15597 | ||
Author | ||
MARWAN M. F. AL-HEETY* | ||
Anbar University - Department of Chemistry - College of EducationAnbar | ||
Abstract | ||
This research concerned with the reaction of Aryl- benzoylchloride with 1,3-cyclohexanedione in aqueous media (which has been catalyzed by p-dodecylbenezenesulfonic acid (DBSA) or sodiumdodecylsulfate (SDS)). The product include two types derivatives : seven compounds from 9-aryl-1, 8-dioxooctahydroxanthene derivatives and seven compounds from 2,2’-arylmethylene Bis-(3- hydroxy- 2-cyclohexene-1-one) derivatives. The Products were diagnosed by the spectral methods (I.R.) and the elements quantities analyses(C.H.N.). Add-on products compound's, This method provides several advantages such as good yield, simple work-up procedure and environment friendly | ||
Keywords | ||
aryl; dioxooctahydroxanthene; methylene bis; hydroxy; cyclohexene; One; aqueous media | ||
References | ||
Anastas P and Williamson T, Green Chemistry, Frontiers in Benign ChemicalSynthesis and Procedures, Oxford Science Publications, 1998 | ||
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