The effect of Cd substitution in PbS thin film on the optical properties | ||
Journal of University of Anbar for Pure Science | ||
Article 19, Volume 3, Issue 3, December 2009, Pages 59-68 PDF (651.53 K) | ||
Document Type: Research Paper | ||
DOI: 10.37652/juaps.2009.15541 | ||
Authors | ||
Hamid S. Al-jumaili; Saeed .N.T.AL-Rashed; Alaa .A.Al-jubory | ||
Anbar University - College of Education for Pure Sciences | ||
Abstract | ||
Abstract:Thin films of CdxPb1-x S were prepared by chemical spray pyrolysis with ( x=0.6 , 0.7 , 0.8 , 0.9 , 1 ) .The optical properties of prepared thin films were studied by UV-VIS spectrophotomer . From the measurement of absorption and transmission , the optical parameters and the optical energy gap (Eg) were calculated .The optical energy gap (Eg) was increased with increasing the value of Cd from 1.2 eV when x=0.6 to 2.4 eV when x=1 . The maximum value of refractive index (n) is equal to 2.5 and the maximum value of extinction coefficient is varied between 0.2 to 0.45 depending on the value of x . The film with x=0.7 was doped by Ag in the ratio 1% ,3% and 5% . The film after dopping have a direct energy gap also and the value of Eg were increased with increasing (Ag) ratio , these values increased from 1.2 eV for absent Ag to 1.74 eV for 5% Ag . | ||
Keywords | ||
Cd substitution; PbS thin film; Optical properties | ||
References | ||
1-P. P. Sahay, R. K. Nath, and S. Tewari, (2007), “Optical properties of thermally evaporated CdS thin films“, Cryst. Res. Technol. 42, No. 3,PP. 275 – 280 .
2- Charita Mehta, Jasim M. Abbas, G. S. S. Saini, S. K. Tripathi ,(2007), ”effect of deposition parameters on the optical and electrical properties of nanocrystalline CdSe“, Chalcogenide Letters Vol. 4, No. 11, pp. 133 – 138 .
3-C.I. Oriaku and J.C. Osuwa.,(2008),”Analysis of Thin Chalcogenide PbS Films Prepared from Chemical Bath”, The Pacific Journal of Science and Technology, Vol. 9, No. 2 , PP 461-467 .
4- M. Fadel, S. S Fouad, E. G. El-Metwally, (2008) “theoreticalobservation on the excremental data of Ge-Se – TI System “Chalcogenide Letters Vol. 5, No. 5, pp.79 – 86.
5 – M.thambidurai, N.murugan , N. muthukumarasamy , S.vasantha, R.balasundaraprabhu, S.agilan, (2009), ” preparation and characterization of nanocrystalline CdS thin films“ Chalcogenide Letters Vol. 6, No. 4, pp. 171 – 179.
6- N. choudhury and B K sarma ,(2009) “ Structural characterization of lead sulfide thin films by means of X-ray line profile analysis “ Bull. Mater. Sci., Vol. 32, No. 1, pp. 43–47.
7-Alaa A.,”study the structural and optical properties of Zn1-xPbxS thin films which preparing chemical spray pyrolysis “Ms.phys. Thesis Al-anbar university (2005).
9-A.popa,M.lisca,V.stancu,M.buda ,E. pentia ,T.potila ,(2006) , " Crystallite size effect in PbS thin films grown on glass substrate by chemical bath deposition ", journal of optoelectronics and advanced material ,Vol.8,No.1, PP.43-45.
8- B. thangaraju , P.kaliannan , (2000),”Polycrystalline Lead Tin Chalcogenide Thin Film Grown by Spray Pyrolysis “ , Cryst. Res. Technol, Vol 35, No. 1, PP. 71 - 75.
10- V.popescu, H. I. nascu , E. darvasi ,(2006) ,” Optical properties of PbS-Cd multilayers and mixed (CdS+PbS) thin films deposited on glass substrate by spray pyrolysis”, jurnal of optoelectronics and advanced material Vol.8, No.3, PP . 1187-1193.
11- Saliha Ilican, Muhsin Zor, Yasemin Caglar , Mujdat Caglar ,(2006) “Optical characterization of the CdZn (S1-xSex)2 thin films deposited by spray pyrolysis method”,Optica applicata, Vol.XXXVI, No.1., pp.29-37. | ||
Statistics Article View: 90 PDF Download: 1,092 |