Synthesis of Calcium-Zincon Complex and Exploitation it in the Assembly of Calcium Ion-Selective Electrode. | ||
| Journal of University of Anbar for Pure Science | ||
| Article 8, Volume 3, Issue 1, April 2009, Pages 21-30 PDF (567.2 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2009.15513 | ||
| Authors | ||
| Khmees A. Al-Eesawi* ; Kaiss R. Ibraheem; Ismail K. Al-Hitti | ||
| University of Anbar. College of science | ||
| Abstract | ||
| A new calcium ion-selective electrode was assembled from complex synthesized by calcium ion and zincon which doped in pvc with suitable mediator and solvent . The prepared complex was identified by UV- Visible and IR spectrophotometry. The new electrode was characterized by its high slope (29.55 ±0.02 mV/decade) compared with calcium phosphate electrode (26.67±0.022 mV/decade) and long lifetime (10 months) . The linear range of the electrode was 10-5-10-1M and the detaction limit was 10-5M . Response time was in the range of 20-60 seconds depending on the concentration of the solution and the lifetime of the electrode. The electrode was linearly working at a pH of (5-10). Most of anions were severely interfered and these were exploited to determine calcium and the anions in precipitation titrations . Cations were slightly interfered especially at high interferent concentrations . The new electrode was applied for the determination of calcium in tap water which offered excellent results compared with flame emission photometric method . | ||
| Keywords | ||
| calcium ion; Selective Electrode; ISE; Zincon; poly; Liquid ion exechanger; Neutral carriers; Tetra hydro furan | ||
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