SYNTHESIS AND PHOTOLYSIS OF SOME TRANSITION METAL COMPLEXES OF SCHIFF BASE LIGAND DERIVED FROM ETHYLENEDIAMINE AND SALICYLICALDEHYDE | ||
| Journal of University of Anbar for Pure Science | ||
| Article 6, Volume 1, Issue 1, April 2007, Pages 21-27 PDF (229.96 K) | ||
| DOI: 10.37652/juaps.2007.15485 | ||
| Authors | ||
| WALEED.F. AL-HITY1; KAISS .R. IBRAHEEM2; MOHAMMED A.AL-HADITHI2 | ||
| 1CHEM.DEPT.COLL. OF EDUCATION FOR WOMEN, UNIVER. OF AL-ANBAR | ||
| 2CHEM.DEPT.COLLEGE OF SCIENCE, UNIVERSITY OF AL-ANBAR | ||
| Abstract | ||
| This study deals with the preparation of Schiff- base ligands from the reaction of salicaldehyde with ethylenediamine in the ratios 1:1 of ligand (1) and 1:2 of ligand (2). Their metal complexes with ions Fe (11), Co (11), Ni (11), and Cu (11) were also prepared. The electronic spectrum of all these complexes and the IR spectrum were studied. The ratios of dissociation of these complexes were investigated via radiation by using mercury lamp in the wavelength of 365 nm. It is noticed that these complexes dissociate slowly during the process of radiation. | ||
| Keywords | ||
| Schiff; base ligands; Electronic spectra; Structural Formulas; photolysis | ||
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