NOVEL STUDY FOR CHEMICAL COMPOSITION OF AL-AHDAB CRUDE OIL | ||
| Journal of University of Anbar for Pure Science | ||
| Article 10, Volume 11, Issue 3, December 2017, Pages 40-48 PDF (632.34 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2017.145541 | ||
| Authors | ||
| Tariq A. Al-Ani1; Mohsin O. Mohammed2; Abrahim H. Farhan* 1 | ||
| 1College of Science, University of Anbar | ||
| 2College of Science, University of Kirkuk | ||
| Abstract | ||
| Thisn research included determination of chemical composition of al-ahdaab crude oil (kute- Iraq) using liquid – solid chromatography. The current researched included to separation the component of crude oil by column chromatography was packing with alumina (AL2O3) as a stationary–phases and several solvent as a mobile phase. . The results of crude oil fractionations were 17.01% Asphaltene, 82.99% Maltene, which separated to (Paraffinic) (saturated) 44.11%, Aromatic 30.11% and Resin 4.20%. Crude oil fractionation were characterized using Nuclear Magnetic Resonance H1NMR and Fourier Transform Infrared Spectrometer FT-IR to determine the chemical composition of each part, which is that represents the first study and a novel results. This study also clarified the paraffinic compounds are represented the main part of materials in crude oil composition. | ||
| Keywords | ||
| crude oil; fractionation; chemical composition; Ahdab | ||
| References | ||
|
1- Mustafa Versan Kok. Characterization of medium and heavy crude oils using thermal analysis techniques, (2011) . Fuel Processing Technology 92 1026–1031.
2- Mahinpey N, Murugan P, Mani T, Comparative kinetics and thermal behavior: the study of crude oils derived from Fosterton and Neilburg Fields of Saskatchewan, (2010) Energy Fuels 24-3m 1640–1645.
3- Mamdouh T. Ghannama, Basim Abu-Jdayil. Rheological properties of heavy & light crude oil mixtures for improving flow ability, (2012) Journal of Petroleum Science and Engineering 81 122–128.
4- Bouhadda Y, Bormann D, Sheu E, et al. Characterization of Algerian Hassi-Messaoud asphaltene structure using Raman spectrometry and X-ray diffraction,( 2007 )[J].Fuel, 86: 18551864.
5- Enekwe, Chukwudi Benedict1 and Okoro, Hyceinth Akpa. Analytical studies of poor performance of research, (2013) Volume 3, Issue 3.
6- May- Elena Dominguez-Rosado and John Pichtel. (2003), chmical characterization of fresh Weathered motor oil Proceedings of the Indiana Academy of Science 112(2) :109–11 6.
7- Joseph D. McLean and Peter K. Kilpatrick. Comparison of Precipitation and Extrography in the Fractionation of Crude Oil Residua, (1997) Energy & Fuels,11,570-585.
8- Carmen Garcia el, M.; Carbognani, L.; Orea, M. & Urbina A. (2000). The Influence of Alkane Class-Type on Crude Oil Wax Crystallization and Inhibitors Efficiency Journal of Petroleum Science and Engineering, Vol.25, No.3-4,pp.99-105, ISSN 0920-4105.
9- Odebunmi E.O, Ogunsatin E.A, characterization of crude oil and petroleum products elution liquid chromatographic separation. (2000), Bull. chem. Soc. Ethiop, 6 (2)115-132.
10- Ren Wenpo, Shan Honghong, Yang Chaohe. Characterization of Average Molecular Structure of Heavy Oil Fractions) 2006) China Petroleum Processing and Petrochemical Technology Ren Wenpo Yang ,Vol. 13, No. 3, pp 1-7.
11- Trejo F, Ancheyta J, Morgan T J, et al. Characterization of asphaltenes from hydrotreated products by SEC, LDMS MALDI, NMR, and XRD, (2007) [J]. Energy & Fuels, 21(4((228-2121) .
12- -Elham Keshmirizadeh1, Somayeh Shobeirian, Mahmoud Memariani Determination of Saturates, Aromatics, Resins and Asphaltenes (SARA) Fractions in Iran Crude oil Sampl, Study of the Geochemical Parameters, (2013), Journal of Applied Chemical Research, 7, 4, 15-24.
13- Ren Wenpo, Yang Chaohe, Shan Honghong. Characterization of Average Molecular Structure of Heavy Oil Fractions by 1H Nuclear Magnetic and X-ray Diffraction. (2011), China Petroleum Processing and Petrochemical Technology Vol. 13, No. 3, pp 1-7.
14- Ahammed, M. A., Tighe, S., (2011). Asphalt pavements surface texture and National Research, Council, Ottawa, in press, Volume 39 1-9.
15- AkmzA, S. Iscan, O. Gurkaynak, M. A., and Yasar, M. The Structural Characterization of Saturate, Aromatic, Resin, and Asphaltene Fractions of Batiraman Crude Oil, (2011) Petroleum Science and Technology, 29:160–171.
16- --Fredericks,P.M.,J.B.Lee, P.R,Osborn,and D.A.Swinkels, Materials characterization using factor analysis of FTIR spectra.Part2: mathematical and statistical consideration)ز 1989). Applied Spectroscopy, v39, n2, pp311-315
17- Annual Book of American Society for Testing and Materials Standards, (1986). Comparison of water borne petroleum oils by Infrared spectroscopy. ASTMD 3414-80 (reapproved (1985), vll. 02, pp 329-339.
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