Synthesis and characterization Of Bridged phthalocyanine & tetra pyrazino Porphyrazine complexes of Iron(III) and their copolymer | ||
Almuthanna Journal of Pure Science (MJPS) | ||
Article 1, Volume 2, Issue 1, December 2014, Pages 0-0 | ||
Authors | ||
Nazar A. Hussien and; Hasan Sabeeh Jabur | ||
Abstract | ||
A two types of bridged complexes of Iron (III) with two types of ligands phthalocynine & tetrapyrazino Porphrazine were prepared according to adjusted procedure as in the litratures to forms a two complexes , Phthalocyanina to separately Iron(III) chloride[I] and tetrapyrazino Porphrazine iron (III) chloride[II] were converted to phthalocyanato Iron(III) hydroxide [III] and tetrapyrazino Porphrazine Iron(III) hydroxide[IV] separately. The hydroxide complexes then converted to the bridged polymeric fluoride complexes [V] and [VI] .The copolymer [VII] were prepared from the mixed of hydroxide complexes [III] and [IV] of(1:1) ratio to the polymeric fluoride of two ligands .The compounds then characterized by elemental analysis and spectroscopic methods. | ||
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