ISOTHERM ADSORPTION STUDY OF THE SOME DICARBOXYLIC ACID BY MANGANESE DIOXIDE | ||
| Journal of University of Anbar for Pure Science | ||
| Article 20, Volume 8, Issue 1, April 2014, Pages 75-100 | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2014.122706 | ||
| Authors | ||
| KHALEL I. AL-NIEMI; IBRAHIM Y. MOHAMMED; SAFWAN AL-DOBONI | ||
| University of AlMosul ,Collage of Education | ||
| Abstract | ||
| The adsorption process for Aliphatic and Aromatic dicarboxylic acid on manganese dioxide was studied briefly as a polluted material which produced in nature. The result showed that the anions of acid molecules were adsorbed on the surface of MnO2 depending on the pH of the solution and the shape of molecule. The aliphatic acids were partially enforcement with Langmuir isotherm and completely with Freundlech isotherm, but phthalic acid agreed with Langmuir only. The kinetic studies of pseudo first and second order were applied on this system. The adsorption process was endothermic except succinic acid, non- spontaneous and the nature of forces between the acid molecules and surface were physical in nature ,where the molecules in continues motion on surface and unsystematic except for succinic acid. | ||
| References | ||
|
1-L.B.Khalil and B.S.Girgis(1998)."Color removal of some dyastuffs by activated carbon derived from apricol stone shells". Adsorpt. Sci, Tehnol., 16:P.P405-414
2-G.M.Walker and L.R.Weatherley (1997)."Process Biochem". 32,No.4, p.p327-335
3-S.Skrabakova and E.Matisova (1995). "Carbon Sorbent for the preconcentrotion of organic pollutants". from Environmental matrices (in Czech) chem. Listy,89.
4-الحسینی هیفاء جاسم (2006)"امتزاز بعض الصبغات على سطوح أکاسید الحدید، النحاس،الخارصین، الألمنیوم ".رسالة ماجستیر، التربیة للبنات، جامعة الکوفة. 5-Weaver RM, Hochella JMF. (2003). "The reactivity of seven Mn-oxides with Cr3+aq: A comparative analysis of a complex". environmentally important redox reaction. Am Miner 88:2016–2027.
6-W.Stumm and J.J.Morgan(1996).
"Aquatic Chemistry, Chemical Equilibria and Rator in Natural Water". 3rd ed.John Wiley and Sons.Inc.
7-النعیمی،خلیل إبراهیم عبدالله وأسماء موفق"دراسة الامتزاز الایزوثیرمی لبعض الحوامض الامینیة باستخدام ثنائی اوکسید المنغنیز".المؤتمر العلمی الثانی للکیمیاء_کلیة العلوم_جامعة الموصل 22-23/11/2011 ص 575-598 . 8-K.A.Ahmed(2008). "Study the effects influencing the adsorption of Toludine Blue Dye on to MnO2Surface". National Journal of Chemistry Vol.(30)
9-K.Davor,K.Ivan and K.Nikola (1998). "adsorption of organic acids on metal oxides" .The Umberrellaeffect, Croatica Chemica,71:4:1139- 1153 .
10-S.Bernard , ph.Chazal and M.Mazet (1997 ) ."Removal of organic compounds by adsorption on pyrolusite (B-MnO2)".Water Res.Vol.31:lssue 5:1216-1222.
11-A.T.Shone(1987)."Reductive dissolution of Manganese(III/IV) oxides by substitted phenols". Environ ,Sci. Technol.,21: 979-988. 12- T.J.Jones and R.M.Noyer (1983)."Mechanistic detailes of the oxidation of oxalate by Manganese III". J.phys.Chem.87: 4686-4689.
13- L.D.Newton and R.D.Devaney (2004)"Encyclopedia of surface and colloidial science".
14- إبراهیم،محمد نزار وخالد محمود ومروان محمود(1988)."الکیمیاء العضویة". دار الکتب للطباعة والنشر-جامعة الموصل. 15- G.C.Pimental and A.L.McClellan (1960)."The hydrogen Bond". Freeman W.H. San Franciscow,169-195.
16- A.B.Uddin, M.H.Sujari, A.M.Nawi (2003). "Effectiveness of Peat Cagulant for the removal of textile ryes from aqueous solution and textile waste water".Malaysin, J.Chem.5:p.35 .
17- I.Arvanitoyannis, I.Eleftheriadis and E. Tsatsaronis (1989). "Influence of pH on adsorption of dye- Containing effluents with different bentonites". Chemosphere,18: 1707- 1711.
18- عبدالله ،خالد احمد وخلیل إبراهیم النعیمی وعمار احمد حمدون(2004)."دراسة امتزاز بعض الحوامض العضویة من محالیلها المائیة باستخدام کاربون منشط محضر بالمعالجة الکیمیائیة" .مجلة التربیة والعلم, المجلد16: العدد3. 19-Z.Bouberka, S.Kacha, M.Kameche, S.Elmaleh and Z.Derriche (2005). "Sorption study of an acid dye from an aqueous solutions using modified clays". J Hazard Mater B 119:117– 124
20- M.Afzal and A.Nasser(1972). "Adsorption of organic acids from aqueous solution on charcoal". Pakistan J.Sci.Res. Vol.15:NO.3:137- 139 .
21- Y.S.Ho, G.Mckay, D.A.J.Wase and C.F.Foster(2000)."Study of the Sorption of divalent metal ion onto peak".Adsorp.Sci.Technol,18: 639-650.
22- G.Makay and Y.S.Ho(1999). "Pseduo second order model for adsorption process". Process Biochem.24: 451-465.
23- صالح ،جلال محمد (1980)."کیمیاء السطوح و العوامل المساعدة"جامعة بغداد. 24- P.Janos , H.Buctova andM.Ryznarova (2003)."Water Res.".37:4938-4944 .
25- D.Mohan, K.P.Singh and K.Kumar (2002)."Removal of Dyes from wastewater using flyash alow-Cost adsordent".Ind.Eng.Chem.Res.41:3688-3695.
26- النعیمی ،خلیل إبراهیم وصفوان عبدالستار الدبونی وذکى عبدالغنی2011)). "تاثیر استخدام MnO2 کمادة مازة على ثابت التأین والتوصیل الکهربائی لبعض الحوامض الکربوکسیلیة الالیفاتیة الحاویة على مجموعة الهیدروکسیل فی الموقع( α )". مجلة جامعة الانبار للعلوم الصرفة, المجلد5:العدد(3 ). 27-Mckay G.H.,Blair S. and Gardenar J.K.,"The adsorption of dyes on to Chitin in fixed bed column and batch adsorbens", J.App.Polym.Sci 28,p.p 1499-1544,(1989).
28- التمیمی، عصام حسین علی(2003)."تحضیر ودراسة معقدات بولیمر الکاؤولین-یوریا-فورمالدیهاید, حرکیة امتزاز بعض المرکبات الفینولیة من محالیلها المائیة". رسالة ماجستیر-جامعة بغداد. 29-V.p. Rovi, R.V.Jasra and T.S. G.Bhat (1998)."Adsorption of phenol,cresol isomers and benzylalcohol from aqueous solution on activated carbon at 278,298 and 323 k°".J.chem. Technol.Biotechnol, 71:No.21:173-179 .
30-S.Lagergren (1898)."About thetheory of So called adsorption of soluble substance". K.Sevenskevetenskapsakad. H.,Band 24:4:1-39 .
31- G.Mckay and Y.S.Ho (1999). "Pseudo- second order model for a sorption processes". Process Biochem.,24: 451-465 .
32- G.Eli, J.Edward and E.Kita(1974). " Analytical chemistry".46:11: 1370-1375. | ||
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