Interaction between Kaolin and DMSO: FTIR, XRD , thermodynamic and Nano studies | ||
| Journal of University of Anbar for Pure Science | ||
| Article 9, Volume 8, Issue 1, April 2014, Pages 32-40 | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2014.121534 | ||
| Authors | ||
| Sabri M. Hussein1; Omar H. Shihab2; Sattar S. Ibrahim3 | ||
| 1University of Anbar – College of Science. | ||
| 2University of Anbar – College of Women Education. | ||
| 3University of Anbar – College of Science | ||
| Abstract | ||
| Intercalation of highly polar organic compound dimethylsulfoxide (DMSO) with kaolinite and the formation of interlamellar complexes has been studied, and characterized by X-ray diffraction (XRD), Fourier transform-infrared spectroscopy (FTIR). Interaction was found to be dependent on the particle size of kaolin raw material. Nature of interaction achieved through the formation of hydrogen bonds between DMSO and both AlOH and Si – O surface of kaolinite. Effect of temperature on equilibrium adsorption of methylene blue (MB) from aqueous solution using kaolin and kaolin – DMSO complexes also studied, the results were analyzed by Langmuir and Freundlich isotherms. Thermodynamic parameters such as ΔG, ΔH and ΔS were calculated. Results suggested that the MB adsorption on kaolin was spontaneous and exothermic process. | ||
| Keywords | ||
| organo; clays; Intercalation; adsorption; adsorption isotherms; Dyes; FTIR; XRD; TEM | ||
| References | ||
|
[1] C. Belver, M.A. Munor, M.A. Vicente, Chem. Mater, 2002, 14 2033-2043.
[2] G. Vaga, Epitoanyag,2007, 59, 4-8.
[3] A.M. Caulcante, L.G Torres, G.L.V. Welho, Braz. Journal of Chemical Engineering, 2005, 22, 2682-2865.
[4] T.O. Salawudeen, E.O. Dada, S.O. Alagbe, Journal of Engineering and Applied Sciences, 2007, 2, 11, 1677-1680.
[5] W.A. Deer, R.A. Howie, J. Zussman, An introduction to rock forming minerals, Harlow longman 1992.
[6] G. Stephen, R.T. Martin, clay and clay minerals, 1995, 43, 2, 225-226.
[7] A. Coma, A. Misfud, E. Sanz, clay miner, 1990, 25, 19.
[8] S. Yariv, Organo-clay Complexes and Interactions, S. Yariv and H. Cross, Eds, Marcel Dekker, New York 2002, p. 90.
[9] J. Kristóf, R. L. Frost, J. T. Kloprogge, E. Horváth and M. Gábor, J. Therm. Anal. Cal., 56 (1999) 885.
[10] S. Yariv, I. Lapides, A. Nasser, N. Lahav, I. Brodsky and K. H. Michaelian, Clays Clay Miner., 48 (2000) 10.
[11] S. Yariv and I. Lapides, J. Therm. Anal. Cal., 80 (2005) 11.
[12] Z. Yermiyahu, I. Lapides and S. Yariv, Appl. Clay Sci., 30 (2005) 33.
[13] Janek M, Emmerich K, Heissler S, Nuesch R. Thermally induced grafting reactions of ethylene glycol and glycerol intercalates of kaolinite. Chem Mater. 2007;19:684–93.
[14] Frank Caruso. Chemistry of materials 20 years on and on the rise. Chem Mater. 2008;20:1–2.
[15] Letaief S, Elbokl TA, Detellier C. Reactivity of ionic liquids with kaolinite: Melt intersalation of ethyl pyridinium chloride in an urea-kaolinite pre-intercalate. J Colloid Interface Sci. 2006;302:254–8.
[16] Tonle IK, Diaco T, Ngameni E, Detellier C. Nanohybrid kaolinite-based materials obtained from the interlayer grafting of 3-aminopropyltriethoxysilane and their potential use as electrochemical sensors. Chem Mater. 2007; 19: 6629–36.
[17] Gardolinski JE, Ramos LP, Desouza GP, Wypych F. Intercalation of benzamide into kaolinite. J Colloid Interface Sci. 2000;221:284–90.
[18] Fang QH, Huang SP, Wang WC. Intercalation of dimethyl sulphoxide in kaolinite: molecular dynamics simulation study. Chem Phys Lett. 2005;411:233–7.
[19] R. K. Vempati, M. Y. A. Mollah. G. R. Reddy, D. L. Cocke, H. V Lauer. Jr., J. Mater. Sci. 31 (1996) 1255.
[20] Gardoliski, J., Filho, H. P. M. and Wypych, F. ( 2003 ) Thermal behavior of hydrated kaolinite. Quim. Nova., 26 (1): 30 – 35.
[21] J. G. Thompson and C. Cuff. Clays Clay miner. 33. 490 (1985).
[22] S. Olejnik, L. A. G. Alymore. A. M. Posner, and J. P. Quirk, J. Phys. Chem. 72, 214 (1968).
[23] M. Raupach, P. E. Baron, and J. G. Thompson, Clays Clay Miner. 35, 208 (1987).
[24] X. Zhang and Z. Xu. Mater. Lett. 61, 1478 (2007).
[25] S. Yariv and I. Lapides, J. Therm. Anal. Cal. 94, 433 (2008).
[26] I. Lapides and S. Yariv, J. Therm. Anal. Cal. 97, 19 (2009).
[27]Dilek AKAR, Msc. Thesis. " Physiochemical characterization of the sorption of Cr3+ and Sr3+ ions on natural kaolinite and Clinoptilolite minerals (2005) pp.77. | ||
|
Statistics Article View: 2,388 PDF Download: 144 |
||