Preparation and Characterization of New Mixed Ligand Complexes of (p-Methyl Anilino)-p-Chloro Phenyl Acetonitrile and Ethylene Diamine | ||
| Iraqi Journal of Science | ||
| Article 1, Volume 57, Issue 4, October 2016, Pages 2592-2603 | ||
| Authors | ||
| ; a Abass Majeed | ||
| Abstract | ||
| New mixed ligand complexes of some metal ions Zn(II), Cd(II) and Hg(II) were prepared by reacting with mixture of two bidentate ligands [ HL = (P-methyl anilino) –P– chloro phenyl acetonitrile and en = ethylene diamine] in a molar ratio of 1:1:1[ M : HL : en] in ethanol . The ligand HL was previously prepared by Strecker’s procedure which includes the reaction of p- toluidine with P- chlorobenzaldehyde in the presence of KCN in acidic medium. The structures of new compounds were identified by elemental analyses, atomic absorption and thermal analyses TG/DTG in addition to FTIR and U.V-VIS. Spectra. The electrical conductivity measurements of metal complexes were also determined. From the obtained data the octahedral structure was suggested for all prepared complexes. | ||
| Keywords | ||
| veterinary drugs complexes of mixed ligand; Aminonitrile; and Hg complexes | ||
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