Synthesis, mercuration, and halogenation of some furyl orp-unsaturated | ||
| Tikrit Journal of Pure Science | ||
| Article 1, Volume 19, Issue 1, April 2014, Pages 33-44 | ||
| Authors | ||
| Sabah Hussian Khonheed; Ahmed A.H.Al-kadhimir; Huda Abid thamer Al-badreer | ||
| Abstract | ||
| Abstract The first part of the research includes the preparalion of some a,ftcarbonyl compounds containing furan ring in a basic medium, compounds(l -4), also some difurylidine and furylidine benzylidine compounds have been prepared from furfural and substituted benzaldehydes and cyclohexanone, compounds(5-9) in basic medium . The second part of the research included the mercuration ofThe resulting compounds with mercury (lI) chloride compounds( I 0- 19) followed by symmeterisation with Nal to afford compounds of the form (Fur)rHg (20-28). Some of th€ mercurated compounds have been halogenated via the replacement of-Hgcl by the reaction with iodine, compounds (29-31). The third part of the research included the biological activity of two ofthe prepared compounds (3,4). All of the prepared compounds have been identified by their melting points and lR and IJV spectra and some ofthem by CHNS analysis and NMR techniques. Introduction o,p-unsaturated ketones are important type of carbonyl compounds with the general structure | ||
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