Synthesis and characterization of Pd(II) and Pt(II) complexes containing mixed ligands of thione and diamine | ||
| Tikrit Journal of Pure Science | ||
| Article 1, Volume 21, Issue 7, December 2016, Pages 95-100 | ||
| Author | ||
| Ahmed S. M. Al-Janabi | ||
| Abstract | ||
| New Pd(II) and Pt(II) complexes of the type [M(bzoS)2(diamine)] {where M = Pd(II) or Pt(II) } from the treatment of one mole of the diamine ligands {diamine = , phenanthroline (Phen), bipyridine (Bipy), ethylene diamine (en), or N,N′-dimethyl ethylene diamine (dmen)} with one mole of [M(bzoS)2] complexes. The prepared complexes were characterization by elemental analysis (CHN), molar conductivity, infrared spectroscopy, and nuclear magnetic resonance of proton (1H NMR). The bzoS ligand was bonded as monodentate through the sulfur atom whereas the diamine ligands were bonded as bidentate fashion via the nitrogen atoms to give a square planner arrangement a round to the Pd and Pt ions. | ||
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