Syntheses, Characterization of a New Ligand(3-Hydrazino-N-isopropylidene-5-methyl-4H-1,2,4-trizole-4-amine) and its complex with (Fe(III), Co(III) and Ni(II)) | ||
| JOURNAL OF THI-QAR SCIENCE | ||
| Article 1, Volume 5, Issue 4, December 2016, Pages 65-71 | ||
| Authors | ||
| Muntaha .Y. Hayal; Sajda .S. Affat; Ibrahim .A. Flifel | ||
| Abstract | ||
| The preparation of some, transition metal complexes ( Fe3+, Co3+ and Ni2+) with Novel ligand (3-Hydrazino-N-isopropylidene-5-methyl-4H-1,2,4-trizole-4-amine) .Prepared compounds diagnosed by spectrum ( Infrared(IR) , Nuclear magnetic resonance (1HNMR) , and Mass spectra (MS) ) and analytical techniques (Elemental analyses (CHN) , Conductivity measurements) .Each data explained in the tables (2,3 and 4) .We were able to determine the consistency through the infrared spectrum data show us that consistency is happening through amine and azomethine groups as illustrated in Figure (1) . This conclusion is confirmed by the diagnosis of a new absorption packages at (542, 534, 530) and (289, 270, 262) back to M-N and M-Cl respectively .Were not present in the spectrum ligand back to the central atom with two atoms of nitrogen consistency and the results were identical to what is practically expected. from all the outcome can be concluded the octahedral geometry of Fe3+and Co3+ complexes,, while Ni+2 complex were tetrahedral geometrics. | ||
| Keywords | ||
| Conductance; Spectroscopic methods; Metal Complexes | ||
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