Spectral study of some charge transfer complexes derived from some of drugs and acceptors in different solvents | ||
Diyala Journal For Pure Science | ||
Article 1, Volume 10, Issue 3, October 2014, Pages 98-113 | ||
Authors | ||
S. D. Quddori; I. K. J. Al-dhmashee; A. A. K Al-Taiee | ||
Abstract | ||
New charge-transfer (CT) complexes(10) were prepared from 3- methoxy 4- hydroxyl benzyldehyde(vanillin)، dimethyl aminebenzaladehyde with some aromatic amines (sulfa drugs) derivatives compounds as donor molecules with two acceptors molecules dinitrobenzene, and 2,4,6 trinitrophenol. The CT complexes were identified by FT-IR, melting points and UV-Vis spectra. The type of bonding between the donor and acceptor depends on the interaction between components were studies by UV-Vis spectra. The electronic absorption spectra of these compounds have been estimated under different polar solvents, some physical parameters of CT complexes have been calculated at the max of each of them.Using Benesi-Hildebrands equation at25oC, the equilibrium constant has been calculated. | ||
Keywords | ||
Schiff bases; Charge Transfer Complexes; polar solvent | ||
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